The strength of acids and bases is determined by their ability to donate or accept protons (H+ ions) and can be quantified using the concepts of dissociation in water and the corresponding equilibrium constants. Understanding acid and base strength helps predict the behavior of substances in various chemical reactions, essential for fields like chemistry, biology, environmental science, and medicine.
Alfa Chemistry provides the following chart of the strengths of the most common acids and bases for you to look over. We want to help you more easily determine an acid or base's strength.
Ka | Acid | Acid Formula | Base Formula | Base | |||
Large | Perchloric acid | HClO4 | → | H+ | + | ClO4 - | Perchlorate ion |
3.2 * 109 | Hydroiodic acid | HI | → | H+ | + | I- | Iodide |
1.0 * 109 | Hydrobromic acid | HBr | → | H+ | + | Br- | Bromide |
1.3 * 106 | Hydrochloric acid | HCl | → | H+ | + | Cl- | Chloride |
1.0 * 103 | Sulfuric acid | H2SO4 | → | H+ | + | HSO4 - | Hydrogen sulfate ion |
2.4 * 101 | Nitric acid | HNO3 | → | H+ | + | NO3 - | Nitrate ion |
-- | Hydronium ion | H3O+ | → | H+ | + | H2O | Water |
5.4 * 10-2 | Oxalic acid | HO2C2O2H | → | H+ | + | HO2C2O2- | Hydrogen oxalate ion |
1.3 * 10-2 | Sulfurous acid | H2SO3 | → | H+ | + | HSO3 - | Hydrogen sulfite ion |
1.0 * 10-2 | Hydrogen sulfate ion | HSO4 - | → | H+ | + | SO4 2- | Sulfate ion |
7.1 * 10-3 | Phosphoric acid | H3PO4 | → | H+ | + | H2PO4 - | Dihydrogen phosphate ion |
7.2 * 10-4 | Nitrous acid | HNO2 | → | H+ | + | NO3 - | Nitrite ion |
6.6 * 10-4 | Hydrofluoric acid | HF | → | H+ | + | F- | Fluoride ion |
1.8 * 10-4 | Methanoic acid | HCO2H | → | H+ | + | HCO2 - | Methanoate ion |
6.3 * 10-5 | Benzoic acid | C6H5COOH | → | H+ | + | C6H5COO- | Benzoate ion |
5.4 * 10-5 | Hydrogen oxalate ion | HO2C2O2- | → | H+ | + | O2C2O2 2- | Oxalate ion |
1.8 * 10-5 | Ethanoic acid | CH3COOH | → | H+ | + | CH3COO | Ethanoate (acetate) ion |
4.4 * 10-7 | Carbonic acid | CO3 2- | → | H+ | + | HCO3 - | Hydrogen carbonate ion |
1.1 * 10-7 | Hydrosulfuric acid | H2S | → | H+ | + | HS- | Hydrogen sulfide ion |
6.3 * 10-8 | Dihydrogen phosphate ion | H2PO4 - | → | H+ | + | HPO4 2- | Hydrogen phosphate ion |
6.2 * 10-8 | Hydrogen sulfite ion | HS- | → | H+ | + | S2- | Sulfite ion |
2.9 * 10-8 | Hypochlorous acid | HClO | → | H+ | + | ClO- | Hypochlorite ion |
6.2 * 10-10 | Hydrocyanic acid | HCN | → | H+ | + | CN- | Cyanide ion |
5.8 * 10-10 | Ammonium ion | NH4 + | → | H+ | + | NH3 | Ammonia |
5.8 * 10-10 | Boric acid | H3BO3 | → | H+ | + | H2BO3 - | Dihydrogen carbonate ion |
4.7 * 10-11 | Hydrogen carbonate ion | HCO3 - | → | H+ | + | CO3 2- | Carbonate ion |
4.2 * 10-13 | Hydrogen phosphate ion | HPO4 2- | → | H+ | + | PO4 3- | Phosphate ion |
1.8 * 10-13 | Dihydrogen borate ion | H2BO3- | → | H+ | + | HBO3 2- | Hydrogen borate ion |
1.3 * 10-13 | Hydrogen sulfide ion | HS- | → | H+ | + | S 2- | Sulfide ion |
1.6 * 10-14 | Hydrogen borate ion | HBO3 2- | → | H+ | + | BO3 3- | Borate ion |
-- | water | H2O | → | H+ | + | OH- | Hydroxide |
Acid Strength
Strong Acids
- Definition: Completely ionize in water.
- Examples: Hydrochloric acid (HCl), sulfuric acid (H2SO4), nitric acid (HNO3).
- Behavior in Water: HCl → H+ + Cl-
Weak Acids
- Definition: Partially ionize in water.
- Examples: Acetic acid (CH3COOH), formic acid (HCOOH).
- Behavior in Water: CH3COOH ⇌ H+ + CH3COO-
- Equilibrium Constant (Ka): The acid dissociation constant, Ka, measures the strength of a weak acid.
Base Strength
Strong Bases
- Definition: Completely dissociate in water.
- Examples: Sodium hydroxide (NaOH), potassium hydroxide (KOH).
- Behavior in Water: NaOH → Na+ + OH-
Weak Bases
- Definition: Partially ionize in water.
- Examples: Ammonia (NH3), methylamine (CH3NH2).
- Behavior in Water: NH3 + H2O ⇌ NH4+ +OH-
- Equilibrium Constant (Kb): The base dissociation constant, Kb, measures the strength of a weak base.
Other Strength Related Knowledge
Relationship between Ka and Kb
For a conjugate acid-base pair:
Kw is the ion product of water: 1.0 × 10-14 at 25°C.
Indicators of Strength
Strong Acids/Bases: High Ka or Kb, low pH (acids) or low pOH (bases).
Weak Acids/Bases: Low Ka or Kb, higher pH (acids) or higher pOH (bases).