Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

• CAS: 52522-40-4
• Catalog Number: ACM52522404
• Category: Palladium series catalysts
• Molecular Weight: 1035.103g/mol
• Molecular Formula: C52H43Cl3O3Pd2
• Synonyms: Tris(dibenylideneacetone)dipalladium-chloroform; tris-(dibenzylideneacetone)-dipalladium(o)-chloroform adduct; tris(dibenzylideneacetone)-dipalladium (0) chloroform adduct; DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT; tris(dibenzylideneacetone) dipalladium(0)chloroform adduct; GC10022; I14-10041; tris(dibenzylideneacetone) dipalladium chloroform; tris(dibenzylideneacetone)dipalladium (0)chloroform adduct; S-3159
• IUPAC Name: chloroform;(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium
• Canonical SMILES: C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C(Cl)(Cl)Cl.[Pd].[Pd]
• InChI: InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;/b3*13-11+,14-12+
• InChI Key: LNAMMBFJMYMQTO-FNEBRGMMSA-N
• Application: Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.; ; Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).; ; Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2'biphenylylene ditriflates.; ; Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.; ; Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.; ; Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.; ; Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.; ; Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.; ; Palladium catalyst for asymmetric addition of oxindoles and allenes.; ; Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.; ; Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.; ; Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.
• Storage: 0-6°C
• Complexity: 280
• Covalently-Bonded Unit Count: 6
• Defined Bond Stereocenter Count: 6
• EC Number: 610-856-2
• Exact Mass: 1034.035g/mol
• H-Bond Acceptor: 3
• Heavy Atom Count: 60
• Monoisotopic Mass: 1032.035g/mol
• Rotatable Bond Count: 12
• Topological Polar Surface Area: 51.2A^2