Structure

Tin

CAS
7440-31-5
Catalog Number
ACM7440315-4
Category
Nanoparticles & Nanopowders
Molecular Weight
118.71
Molecular Formula
Sn

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Specification

Description
White TIN is an almost silver-white, ductile, malleable, lustrous solid. mp 232° C, bp: 2507°C. Density: 7.3 g/cm³. Pure white tin becomes non-metallic powdery gray tin if held for a sustained period at temperatures less than 13°C.;DryPowder; DryPowder, OtherSolid; DryPowder, PelletsLargeCrystals, OtherSolid; OtherSolid; OtherSolid, Liquid;WHITE CRYSTALLINE POWDER.;Gray to almost silver-white, ductile, malleable, lustrous solid.;Appearance and odor vary depending upon the specific organotin compound.;Gray to almost silver-white, ductile, malleable, lustrous solid.
Synonyms
Tin Powder,Tin element
IUPAC Name
tin
Canonical SMILES
[Sn]
InChI
1S/Sn,ATJFFYVFTNAWJD-UHFFFAOYSA-N
InChI Key
ATJFFYVFTNAWJD-UHFFFAOYSA-N
Boiling Point
4545 °F at 760 mm Hg (NIOSH, 2016);2507 °C
Melting Point
231.9 °C (lit.)
Density
7.28 (NIOSH, 2016);7.265 (white); 5.769 (gray);7.2 g/cm3;7.28;7.28
Solubility
Insoluble (NIOSH, 2016);SOL IN HYDROCHLORIC ACID, SULFURIC ACID, AQUA REGIA, ALKALI; SLIGHTLY SOL IN DIL NITRIC ACID; INSOL IN WATER;Solubility in water: none;Insoluble
Application
At ordinary temperatures tin is stable in air. It actually forms a very thin protective oxide film. In powder form, and especially in the presence of moisture, it oxidizes. When heated with oxygen it forms tin(IV) oxide, SnO2.Tin reacts with all halogens forming their halides. Reaction with fluorine is slow at ordinary temperatures; however, chlorine, bromine and iodine readily react with the metal.

Tin is attacked by concentrated acids. With dilute acids the reaction may be slow or very slow. The metal readily reacts with hot concentrated hydrochloric acid and aqua regia but slowly with cold dilute hydrochloric acid. The reaction also is slow with hot dilute sulfuric acid, which dissolves the metal, particularly in the presence of an oxidizing agent. The reaction with nitric acid is generally slow. Hot concentrated acid converts the metal to an insoluble hydrated tin(IV) oxide. The reaction is rapid with moist sulfur dioxide or sulfurous acid, chlorosulfonic, and pyrosulfuric acids. Organic acids such as, acetic, oxalic, and citric acids react slowly with the metal, particularly in the presence of air or an oxidizing agent.

Strong alkaline solutions of caustic soda or caustic potash dissolve tin forming the stannate, Na2SnO3, or K2SnO3. The metal is stable in dilute solutions of ammonia or sodium carbonate.

Tin dissolves in solutions of oxidizing salts such as potassium chlorate or potassium persulfate. The metal does not react with neutral salts in aqueous solutions. In air, tin reacts slowly with neutral salts.

The metal does not combine directly with hydrogen, nitrogen or ammonia gas.
Storage
room temp
Assay
99.998% trace metals basis
Autoignition Temperature
630 °C (cloud); 430 °C (layer)
Color/Form
Cubic (gray); tetragonal (white); rhomboidal (tin brittle);Almost silver-white, lustrous soft, very malleable & ductile metal; only slightly tenacious; easily powdered; when bent emits crackling "tin cry"; brittle @ 200 °C; brinell hardness 2.9; at -40 °C crumbles to gray amorphous powder (gray tin); slowly changes back above 20 °C to white tin
Complexity
0
Covalently-Bonded Unit Count
1
EC Number
231-141-8
Exact Mass
119.902202g/mol
Form
foil
Formal Charge
0
H-Bond Acceptor
0
H-Bond Donor
0
Heat of Vaporization
296.4 kJ/mol
Heavy Atom Count
1
ICSC Number
1535
MDL Number
MFCD00133862
Monoisotopic Mass
119.902202g/mol
Odor
Odorless
Other Experimental
NATURALLY OCCURRING ISOTOPES: 112 (0.95%); 114 (0.65%); 115 (0.34%); 116 (14.24%); 117 (7.57%); 118 (24.01%); 119 (8.59%); 120 (32.97%); 122 (4.71%); 124 (5.98%);Tin has two allotropic forms at normal pressure; resists distilled, sea and soft tap water; oxygen in soln accelerates attack; when heated in air, tin oxide forms;Heat of fusion: 7.03 kJ/mol /white tin/;Specific Heat: 27.0 J/mol-K (white); 25.8 J/mol-K (grey) @ 25 °C;Thermal conductivity: 0.64 watts/cm °C @ 25 °C, 760 mm Hg;Transformation temp: (beta in equilibrium with alpha) 13.2 °C;Specific heat: 222 J/kg K @ 20 °C;Latent heat of fusion: 7.08 kJ/(g atom);Thermal conductivity: 65 W/m K @ 20 °C;Coefficient of linear expansion: 19.9X10-6 @ 0 °C; 23.8X10-6 @ 100 °C;Shrinkage on solidification: 2.8%;Resistivity of white tin: 11.0 u-Ohm cm @ 0 °C; 15.5 u-Ohm cm @ 100 °C; 20.0 u-Ohm cm @ 200 °C; 22.0 u-Ohm cm @ mp (solid); 45.0 u-Ohm cm @ mp (liquid);Volume conductivity: 15% IACS;Tensile strength, as cast: 14.5 MPa @ 15 °C; 4.5 Mpa @ 200 °C; 20.0 MPa @ -40 °C; 87.5 MPa @ -120 °C
Packaging
100 cm2 in rigid mailer
Physical Description
TIN is a white TIN is an almost silver-white, ductile, malleable, lustrous solid. mp 232° C, bp: 2507°C. Density: 7.3 g/cm³. Pure white tin becomes non-metallic powdery gray tin if held for a sustained period at temperatures less than 13°C.;DryPowder; DryPowder, OtherSolid; DryPowder, PelletsLargeCrystals, OtherSolid; OtherSolid; OtherSolid, Liquid;WHITE CRYSTALLINE POWDER.;Gray to almost silver-white, ductile, malleable, lustrous solid.;Appearance and odor vary depending upon the specific organotin compound.;Gray to almost silver-white, ductile, malleable, lustrous solid.;
Quality Level
100
Rotatable Bond Count
0
RTECS Number
XP7320000
Stability
STABLE IN AIR, BUT WHEN IN POWDER FORM IT OXIDIZES, ESP IN PRESENCE OF MOISTURE;stablilizes <18 °C
Surface Tension
544 mN/m @ mp (231.9 deg C);
Topological Polar Surface Area
0A^2
UNII
387GMG9FH5
UN Number
3089
Vapor Pressure
0 mm Hg (approx) (NIOSH, 2016);1 Pa @ 1224 °C;0 mmHg (approx);0 mmHg (approx)
Viscosity
1.85 mPa-s (=cP)@ 240 °C (MP)
What is the molecular formula of methyl salicylate?

The molecular formula of methyl salicylate is C8H8O3.

What is the molecular weight of methyl salicylate?

The molecular weight of methyl salicylate is 152.15 g/mol.

What is the IUPAC name of methyl salicylate?

The IUPAC name of methyl salicylate is methyl 2-hydroxybenzoate.

What is the InChIKey of methyl salicylate?

The InChIKey of methyl salicylate is OSWPMRLSEDHDFF-UHFFFAOYSA-N.

What is the Chemical Hazard Response Information System (CHRIS) description of methyl salicylate?

Methyl salicylate appears as a colorless, yellowish, or reddish liquid with the odor of wintergreen.

How is methyl salicylate used in terms of acute joint and muscular pain?

Methyl salicylate is used as a rubefacient and analgesic in deep-heating liniments for acute joint and muscular pain.

Where is methyl salicylate naturally produced?

Methyl salicylate is an organic ester naturally produced by many species of plants, particularly wintergreens.

In what year was methyl salicylate first extracted and isolated from the plant species Gaultheria procumbens?

Methyl salicylate was first extracted and isolated from the plant species Gaultheria procumbens in 1843.

What is the FEMA Number for methyl salicylate?

The FEMA Number for methyl salicylate is 2745.

How is methyl salicylate used as a flavoring agent in products like chewing gums and mints?

Methyl salicylate is used as a flavoring agent in chewing gums and mints in small concentrations.

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