Phenoxytrimethylsilane

• CAS: 1529-17-5
• Catalog Number: ACM1529175
• Category: Siloxanes
• Molecular Weight: 166.3 g/mol
• Molecular Formula: C9H14OSi
• Synonyms: Trimethyl(phexy)silane
• IUPAC Name: trimethyl(phenoxy)silane
• Canonical SMILES: C[Si](C)(C)OC1=CC=CC=C1
• InChI Key: OJAJJFGMKAZGRZ-UHFFFAOYSA-N
• Boiling Point: 81 °C(23 mmHg)
• Melting Point: -55 °C
• Flash Point: 52 °C
• Density: 0.92 g/mL
• Appearance: Straw Liquid
• Application: Phenoxytrimethylsilane serves as a versatile chemical intermediate prominently used as a catalyst for the Friedel-Crafts reaction facilitating the transformation of alkenes into alcohols or epoxides Additionally when reacted with hydrochloric acid it yields phenol and chloroform It mirrors the chemical characteristics of phenol including viscosity and resonance spectroscopy properties while also functioning as a trimethylsilyl protected alcohol Notably Phenoxytrimethylsilane is susceptible to forming peroxides upon exposure to oxygen necessitating storage in a cool dry environment shielded from light Studies involving dielectric properties and direct lateral zincation further underscore its utility and adaptability in various chemical applications
• EC Number: 216-211-8
• Exact Mass: 166.08100
• Hazard Statements: Xi: Irritant
• Packaging: 10 g; 100 g
• Packing Group: III
• Safety Description: S26

Custom Q&A

What is the molecular formula of Phenoxytrimethylsilane?

The molecular formula of Phenoxytrimethylsilane is C9H14OSi.

What is the IUPAC name of Phenoxytrimethylsilane?

The IUPAC name of Phenoxytrimethylsilane is trimethyl(phenoxy)silane.

What is the InChI of Phenoxytrimethylsilane?

The InChI of Phenoxytrimethylsilane is InChI=1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3.

What is the InChIKey of Phenoxytrimethylsilane?

The InChIKey of Phenoxytrimethylsilane is OJAJJFGMKAZGRZ-UHFFFAOYSA-N.

What is the canonical SMILES of Phenoxytrimethylsilane?

The canonical SMILES of Phenoxytrimethylsilane is C[Si](C)(C)OC1=CC=CC=C1.

What is the molecular weight of Phenoxytrimethylsilane?

The molecular weight of Phenoxytrimethylsilane is 166.29 g/mol.

What is the hydrogen bond donor count of Phenoxytrimethylsilane?

The hydrogen bond donor count of Phenoxytrimethylsilane is 0.

What is the hydrogen bond acceptor count of Phenoxytrimethylsilane?

The hydrogen bond acceptor count of Phenoxytrimethylsilane is 1.

How many rotatable bonds does Phenoxytrimethylsilane have?

Phenoxytrimethylsilane has 2 rotatable bonds.

What is the topological polar surface area of Phenoxytrimethylsilane?

The topological polar surface area of Phenoxytrimethylsilane is 9.2Ų.

Synthetic Use

Upstream Synthesis Route 1

• 15761-38-3

• 124-38-9
• 1529-17-5
• 6003-05-0
• 115-11-7

Reference: [1] Tetrahedron Letters, 1988, vol. 29, # 3, p. 303 - 306

Downstream Synthesis Route 1

• 7270-63-5
• 64-17-5
• 1529-17-5

• 17138-28-2

Reference: [1] Journal of Organic Chemistry, 2016, vol. 81, # 17, p. 7760 - 7770

Downstream Synthesis Route 2

• 335-05-7
• 1529-17-5

• 17763-67-6

Reference: [1]Justus Liebigs Annalen der Chemie,1973,p. 20 - 32

Downstream Synthesis Route 3

• 375-72-4
• 1529-17-5

• 25628-11-9

Reference: [1]Justus Liebigs Annalen der Chemie,1970,vol. 731,p. 58 - 66

Downstream Synthesis Route 4

• 2426-08-6
• 1529-17-5

• 128886-07-7

Reference: [1]Tetrahedron Letters,1990,vol. 31,p. 1723 - 1726

* For details of the synthesis route, please refer to the original source to ensure accuracy.