1-METHYL-3-TETRADECYLIMIDAZOLIUM CHLORIDE

• CAS: 171058-21-2
• Catalog Number: ACM171058212-2
• Category: Main Products
• Molecular Weight: 314.94
• Molecular Formula: C18H35ClN2
• Synonyms: TetradecMIM Cl, C1C14Im Cl, Im1,14 Cl
• Melting Point: >RT

Case Study

Photocatalytic Decomposition Through TiO2 Microspheres Modified with 1-Methyl-3-Tetradecylimidazolium Chloride Ionic Liquid

Gołąbiewska, Anna, et al. Beilstein Journal of Nanotechnology, 2018, 9(1), 580-590.

By using a solvothermal synthesis method with 1-methyl-3-octadecyl imidazolium chloride ([ODMIM][Cl]) and 1-methyl-3-tetradecylimidazolium chloride ([TDMIM][Cl]), researchers prepared TiO2 microspheres to examine how ionic liquid chain length affects their surface properties and photoactivity. The TiO2 sample synthesized with [TDMIM][Cl] at a molar IL to TiO2 precursor ratio of 1:3 exhibited a photoefficiency four times greater than pristine TiO2. Under visible light irradiation the [TDMIM][Cl] modified suspended TiO2 catalyst achieved a phenol degradation efficiency of 61%.
Photocatalyst Preparation Procedure
The titania precursor titanium(IV) n-butoxide (TBOT) was completely dissolved in absolute ethanol during the stirring process. The mixture received hydrochloric acid together with distilled water and either [ODMIM][Cl] or [TDMIM][Cl] as the ionic liquid. The solution reached a homogeneous and transparent state after stirring the mixture vigorously for 10 minutes. The mixture was moved into a 200 mL Teflon-lined stainless steel autoclave which then underwent a solvothermal reaction at 180 °C for a duration of 24 hours. The product underwent washing with ethanol and deionized water before being dried at 60 °C for 6 hours. Then calcined the resultant powder at 200 °C for 2 hours while increasing the temperature at a rate of 2 °C/min. The molar ratios of ILs to TBOT used in the experiments varied between 1:1 and 1:10.

1-Methyl-3-Tetradecylimidazolium Chloride-Modified Ion Exchange Resins for Adsorption Recovery of Pt(IV)

Bui, Thuy TL, et al. Chemical Papers, 2021, 75, 1567-1579.

In this work, four ionic liquids (ILs, including 1-methyl-3-tetradecylimidazolium chloride ([C14MIM]Cl), 1-n-butyl-3-n-butylimidazolium chloride ([C4BIM]Cl), 1-n-butyl-3-n-tetradecylimidazolium chloride ([C14BIM]Cl), and 1-tetradecylpyridinium chloride ([C14Py]Cl)) were impregnated on ion exchange resin solid supports to prepare supported ionic liquid phase (SILP) adsorbents. These adsorbents recovered Pt(IV) with yields exceeding 90%, with the highest adsorption rate when [C14 MIM]Cl-based SILP was used.
Impregnation of ILs on solid carriers
Four ionic liquids were incorporated into three solid carriers, resulting in 12 distinct types of Supported Ionic Liquid Phases (SILPs). Each SILP was created with ionic liquid loadings (VIL/Vpor ratios) of 10%, 20%, and 30%. For each trial, 5 g of the solid carriers were combined with 25 mL of acetone for 24 hours to create a slurry. The volume of 0.5 M ionic liquid solution required for each experiment was calculated to achieve the desired VIL/Vpor ratio. For instance, to prepare a SILP using SiO2 and [C4BIM]Cl with a 20% ionic liquid loading, 4.79 mL of the 0.5 M ionic liquid solution in acetone was added to the carrier slurry, and the mixture was stirred for 24 hours with a HY-2 Laboratory shaker. Afterward, acetone was removed through slow evaporation to yield the SILP [C4BIM]Cl/SiO2 20%. This method facilitated the preparation of SILPs with VIL/Vpor ratios of 10%, 20%, and 30%. The SILPs were then stored in a desiccator for subsequent sorption experiments.

Custom Q&A

What is the molecular formula of 1-Methyl-3-tetradecylimidazolium chloride?

The molecular formula of 1-Methyl-3-tetradecylimidazolium chloride is C18H35ClN2.

What is the molecular weight of 1-Methyl-3-tetradecylimidazolium chloride?

The molecular weight of 1-Methyl-3-tetradecylimidazolium chloride is 314.9 g/mol.

What are the synonyms of 1-Methyl-3-tetradecylimidazolium chloride?

The synonyms of 1-Methyl-3-tetradecylimidazolium chloride are 171058-21-2, 1-Tetradecyl-3-methylimidazolium chloride, 1-Methyl-3-tetradecyl-1H-imidazol-3-ium chloride, and 1-methyl-3-tetradecylimidazol-1-ium; chloride.

What is the IUPAC name of 1-Methyl-3-tetradecylimidazolium chloride?

The IUPAC name of 1-Methyl-3-tetradecylimidazolium chloride is 1-methyl-3-tetradecylimidazol-1-ium; chloride.

What is the InChI of 1-Methyl-3-tetradecylimidazolium chloride?

The InChI of 1-Methyl-3-tetradecylimidazolium chloride is InChI=1S/C18H35N2.ClH/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-20-17-16-19(2)18-20;/h16-18H,3-15H2,1-2H3;1H/q+1;/p-1.

What is the canonical SMILES of 1-Methyl-3-tetradecylimidazolium chloride?

The canonical SMILES of 1-Methyl-3-tetradecylimidazolium chloride is CCCCCCCCCCCCCCN1C=C[N+](=C1)C.[Cl-].

What is the CAS number of 1-Methyl-3-tetradecylimidazolium chloride?

The CAS number of 1-Methyl-3-tetradecylimidazolium chloride is 171058-21-2.

What are the computed properties of 1-Methyl-3-tetradecylimidazolium chloride?

The computed properties of 1-Methyl-3-tetradecylimidazolium chloride include its molecular weight (314.9 g/mol), hydrogen bond donor count (0), hydrogen bond acceptor count (1), rotatable bond count (13), exact mass (314.2488768 g/mol), topological polar surface area (8.8Ų), heavy atom count (21), formal charge, complexity (206), isotope atom count, defined atom stereocenter count, undefined atom stereocenter count, defined bond stereocenter count, undefined bond stereocenter count, covalently-bonded unit count (2), and if the compound is canonicalized.

What is the Parent Compound of 1-Methyl-3-tetradecylimidazolium chloride?

The Parent Compound of 1-Methyl-3-tetradecylimidazolium chloride is 1-Tetradecyl-3-methylimidazolium.

When was 1-Methyl-3-tetradecylimidazolium chloride created and last modified?

1-Methyl-3-tetradecylimidazolium chloride was created on July 19, 2005, and last modified on October 21, 2023.