Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%

CAS

127593-28-6

Catalog Number

ACM127593286

Category

Palladium series catalysts

Molecular Weight

800.008g/mol

Molecular Formula

C44H32Cl2P2Pd;

MSDS COA Spec Sheet

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Specification

Synonyms

ST24050377; 5353AA; DICHLORO[2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II); 115826-95-4; [(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM (II) CHLORIDE; FT-0696081; MFCD00075254; C44H32Cl2P2Pd; EBD2199625; PALLADIUM, [1,1'-(1R)-[1,1'-BINAPHTHALENE]-2,2'-DIYLBIS[1,1-DIPHENYLPHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)-;

IUPAC Name

dichloropalladium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;

Canonical SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Pd]Cl;

InChI

InChI=1S/C44H32P2.2ClH.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2;

InChI Key

VDHAUMFISVWIRX-UHFFFAOYSA-L;

Application

Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.

Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction.

Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.

Complexity

800

Covalently-Bonded Unit Count

Exact Mass

798.039g/mol

Heavy Atom Count

Monoisotopic Mass

798.039g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2