Specification
Description
Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings.
Synonyms
Allyl carbonate; Carbonic acid, di-2-propenyl ester
Canonical SMILES
C=CCOC(=O)OCC=C
InChI
1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2
InChI Key
JKJWYKGYGWOAHT-UHFFFAOYSA-N
Density
0.991 g/mL at 25 °C (lit.)
Application
Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate.
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Packaging
Packaging
5, 25 g in glass bottle
Refractive Index
n20/D 1.428
Storage Temperature
2-8°C