Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II), methyl-t-butylether adduct, min. 98% [RuPhos Palladacycle Gen. 1]

CAS

1028206-60-1

Catalog Number

ACM1028206601

Category

Palladium series catalysts

Molecular Weight

816.841g/mol

Molecular Formula

C43H65ClNO3PPd;

MSDS COA Spec Sheet

If you have any other questions or need other size, please get a quote.

Specification

Synonyms

Chloro-(2-Dicyclohexylphosphino-2a 6a diisopropoxy-1,1a biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) - methyl-t-butyl ether adduct (RuPhos Precatalyst 1st Gen); 1028206-60-1; Chloro-(2-Dicyclohexylphosphino-2 inverted exclamation marka,6 inverted exclamation marka-diisopropoxy-1,1 inverted exclamation marka-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) - methyl-t-butyl ether adduct; KS-0000005C; Chloro-(2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) - methyl-t-butyl ether adduct (RuPhos Precatalyst 1st Gen); CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',6'-DI-I-PROPOXY-1,1'-BIPHENYL)[2-(2-AMINOETHYLPHENYL)]PALLADIUM(II), METHYL-T-BUTYLETHER ADDUCT;

IUPAC Name

chloropalladium(1+);dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane;2-methoxy-2-methylpropane;2-phenylethanamine;

Canonical SMILES

CC(C)OC1=C(C(=CC=C1)OC(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4.CC(C)(C)OC.C1=CC=C([C-]=C1)CCN.Cl[Pd+];

InChI

InChI=1S/C30H43O2P.C8H10N.C5H12O.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-4H,6-7,9H2;1-4H3;1H;/q;-1;;;+2/p-1;

InChI Key

FINPLSBBDVRBPA-UHFFFAOYSA-M;

Application

Catalyst used in the thermal dehydrogenative Diels-Alder reaction of styrenes.

Catalyst used for the CN-cross coupling reactions of 3-halo-2-aminopyridines.

Catalyst used for the domino reaction of two aryl iodides, involving two C-H functionizations.

Complexity

722

Covalently-Bonded Unit Count

Exact Mass

815.343g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

815.343g/mol

Rotatable Bond Count

Topological Polar Surface Area