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Structure

[μ-Bis(diphenylphosphino)methane]dichlorodigold(I), 99%

CAS
37095-27-5
Catalog Number
ACM37095275
Category
Gold series of catalysts
Molecular Weight
849.232g/mol
Molecular Formula
C25H22Au2Cl2P2;

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Specification

Synonyms
Bis(chlorogold) bis(diphenylphosphino)methane; SC10708; CTK8F8171; ld(I)) bis(diphenylphosphino)methane; Bis(chlorogold(I))bis(diphenylphosphino)methane; AKOS015951028; [MU-BIS(DIPHENYLPHOSPHINO)METHANE]DICHLORODIGOLD(I); Methylenebis[diphenyl]phosphine gold complex;
IUPAC Name
chlorogold;diphenylphosphanylmethyl(diphenyl)phosphane;
Canonical SMILES
C1=CC=C(C=C1)P(CP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Au].Cl[Au];
InChI
InChI=1S/C25H22P2.2Au.2ClH/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;/h1-20H,21H2;;;2*1H/q;2*+1;;/p-2;
InChI Key
JNPUWTQJFLJEJC-UHFFFAOYSA-L;
Application
Catalyst used with chiral counter-ion for asymmetric hydroalkoxylation.

Catalyst used for intramolecular acetylene Schmidt reaction.
Complexity
327
Covalently-Bonded Unit Count
3
Exact Mass
847.991g/mol
Heavy Atom Count
31
Monoisotopic Mass
847.991g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
0A^2
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