Ammonium trifluoromethanesulfonate

• CAS: 38542-94-8
• Catalog Number: ACM38542948
• Category: Metal & Ceramic Materials
• Molecular Weight: 167.11
• Molecular Formula: CH₄F₃NO₃S
• Synonyms: Ammonium triflate
• IUPAC Name: Azanium;trifluoromethanesulfonate
• Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].[NH4+]
• InChI: InChI=1S/CHF3O3S.H3N/c2-1(3,4)8(5,6)7;/h(H,5,6,7);1H3
• InChI Key: BMWDUGHMODRTLU-UHFFFAOYSA-N
• Boiling Point: 225 °C
• Melting Point: 224-226 °C
• Flash Point: 102.2ºC
• Appearance: White crystalline powder
• Storage: Under inert gas (nitrogen or Argon) at 2-8 °C
• Complexity: 145
• Exact Mass: 166.98639865
• Hazard Statements: Xi: Irritant
• H-Bond Acceptor: 6
• H-Bond Donor: 1
• Heavy Atom Count: 9
• Monoisotopic Mass: 166.98639865
• Safety Description: 26-37/39
• Topological Polar Surface Area: 66.6 Ų

Synthetic Use

Upstream Synthesis Route 1

• 358-23-6
• 7664-41-7

• 38542-94-8
• 421-85-2

Reference: [1]Burdon, J.; Farazmand, I.; Stacey, M.; Tatlow, J. C.
[Journal of the Chemical Society][Journal of the Chemical Society, 1957, p. 2574 - 2578]
Gramstad, T.; Haszeldine, R. N.
[Journal of the Chemical Society][Journal of the Chemical Society, 1957, p. 4069 - 4079]
Howells, R. D.; McCown, J. D.
[Chemical Reviews, 1973, vol. 77, p. 69 - 92]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120]

Upstream Synthesis Route 2

• 7664-41-7

• 38542-94-8
• 421-85-2
• 358-23-6

Reference: [1]Burdon, J.; Farazmand, I.; Stacey, M.; Tatlow, J. C.
[Journal of the Chemical Society][Journal of the Chemical Society, 1957, p. 2574 - 2578]
Gramstad, T.; Haszeldine, R. N.
[Journal of the Chemical Society][Journal of the Chemical Society, 1957, p. 4069 - 4079]
Howells, R. D.; McCown, J. D.
[Chemical Reviews, 1973, vol. 77, p. 69 - 92]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120]