Allylaminotrimethylsilane

CAS

10519-97-8

Catalog Number

ACM10519978-3

Category

Main Products

Molecular Weight

129.28 g/mol

Molecular Formula

C6H15NSi

MSDS COA Spec Sheet

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Specification

Synonyms

ALLYLAMINOTRIMETHYLSILANE, N-(Trimethylsilyl)allylamine, 10519-97-8, N-trimethylsilylprop-2-en-1-amine, ACMC-20aluh, AC1MBZSI, 463523_ALDRICH, CTK4A3653, N-(trimethylsilyl)prop-2-en-1-amine, AKOS015909149, KB-74581, Silanamine,1,1,1-trimethyl-N-2-propen-1-yl-, I14-33540

IUPAC Name

N-trimethylsilylprop-2-en-1-amine

Canonical SMILES

C[Si](C)(C)NCC=C

InChI Key

FFJKAASRNUVNRT-UHFFFAOYSA-N

Boiling Point

110-112ºC

Flash Point

10ºC

Density

0.77g/cm³

Appearance

Transparent liquid

Exact Mass

129.09700

Hazard Statements

C: Corrosive;

H-Bond Acceptor

H-Bond Donor

Packaging

10 g; 100 g;

Safety Description

45-36/37/39-25-16-26-23

N-(Trimethylsilyl)Allylamine as Initiator for the Synthesis of Core Cross-Linked Star Polymers

Sulistio, Adrian, et al. Biomacromolecules, 2011, 12(10), 3469-3477.

A core cross-linked star (CCS) polymer has been successfully synthesized, which shows potential for targeted drug delivery. The star polymer was synthesized via a one-pot, arm-first approach using sequential ring-opening polymerization (ROP) of amino acid N-carboxyanhydride (NCA) derivatives initiated with N-(trimethylsilyl)allylamine. Then, the incorporation of allyl functionalities at the star periphery allowed for postpolymerization functionalization with thiolated PEG derivatives via "thiol ene" click chemistry.
Synthesis of CCS Polymers 1 with N-(trimethylsilyl)allylamine
· First, lys NCA (1.00 g, 3.26 mmol) was dissolved in anhydrous DMF (10 mL) in a flame-dried, argon-purged two-necked flask. N-(Trimethylsilyl)allylamine (M/I = 40, 13.7 μL, 0.0817 mmol) was added, and the mixture was stirred at room temperature for 12 h to afford poly(Z-L-lysine) (PZLL) (Mw = 9.67 kDa, PDI = 1.12).
· Cys NCA (MI/CL = 30, 0.716 g, 2.45 mmol) was added, and the mixture was stirred for a further 6 h to afford the crude CCS polymer (Mw = 358 kDa, PDI = 1.73, f = 22).
· This solution was added to AMP (0.283 g, 2.35 mmol) dissolved in DMF (20 mL), stirred for 3 h, and then precipitatied in methanol (250 mL).
· The precipitate was isolated via centrifugation, washed with chloroform (100 mL) and THF (100 mL), and dried in vacuo to afford CCS polymer 1.

August 26, 2023

Stable in nature
Allylaminotrimethylsilane is a very stable silane material, which is very useful in my experiment.

July 21, 2024

High quality precursor for silicon carbonitride films
As a customer in the science research field, I have found Allylaminotrimethylsilane from Alfa Chemistry to be a high-quality precursor for the synthesis of silicon carbonitride films. The product is easy to use in research experiments and has consistently provided excellent results. Additionally, the intermediate has also been very effective in the synthesis of Z-3-(Tributylstannyl)-2-propen-1-amine (T773980). I highly recommend this product for researchers looking for reliable and effective intermediates in their experiments.

What is the molecular formula of allylaminotrimethylsilane?

The molecular formula of allylaminotrimethylsilane is C6H15NSi.

What is the molecular weight of allylaminotrimethylsilane?

The molecular weight of allylaminotrimethylsilane is 129.28 g/mol.

What is the IUPAC name of allylaminotrimethylsilane?

The IUPAC name of allylaminotrimethylsilane is N-trimethylsilylprop-2-en-1-amine.

What is the InChI of allylaminotrimethylsilane?

The InChI of allylaminotrimethylsilane is InChI=1S/C6H15NSi/c1-5-6-7-8(2,3)4/h5,7H,1,6H2,2-4H3.

What is the InChIKey of allylaminotrimethylsilane?

The InChIKey of allylaminotrimethylsilane is FFJKAASRNUVNRT-UHFFFAOYSA-N.

What is the canonical SMILES of allylaminotrimethylsilane?

The canonical SMILES of allylaminotrimethylsilane is C[Si](C)(C)NCC=C.