(4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyl dioxolane

• CAS: 59779-75-8
• Catalog Number: ACM59779758
• Category: Other Products
• Molecular Weight: 246.26
• Molecular Formula: C₁₁H₁₈O₆
• Synonyms: DIETHYL (4R-TRANS)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLATE;(4R,5R)-4,5-DIETHOXYCARBONYL-2,2-DIMETHYL DIOXOLANE;(4R-TRANS)-DIETHYL-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLATE;Diethyl-2,3-o-isopropylidene-L-tartrate;(4r-trans)-2,2-dimethyl-1,3-dioxol
• IUPAC Name: diethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
• Canonical SMILES: CCOC(=O)C1C(OC(O1)(C)C)C(=O)OCC
• InChI Key: MCNKHXZIPATURB-HTQZYQBOSA-N
• Boiling Point: 92-93ºC
• Flash Point: 120.2ºC
• Density: 1.132g/cm³
• Exact Mass: 246.11000
• H-Bond Acceptor: 6
• H-Bond Donor: 0
• Physical Description: (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane 97% (2.5g)
• Safety Description: S24/25

Synthetic Use

Downstream Synthesis Route 1

• 59779-75-8

• 73346-74-4

Reference: [1] Chemistry Letters, 1989, p. 1619 - 1622

Downstream Synthesis Route 2

• 59779-75-8

• 32305-98-9

Reference: [1] Tetrahedron Letters, 1993, vol. 34, # 28, p. 4523 - 4526
[2] Journal of Organic Chemistry, 1980, vol. 45, # 15, p. 2995 - 2999

Downstream Synthesis Route 3

• 59779-75-8
• 62-53-3

• 620-81-5

Reference: [1]Shainyan; Ustinov; Bel'skii; Nindakova
[Russian Journal of Organic Chemistry, 2002, vol. 38, # 1, p. 104 - 110]

Downstream Synthesis Route 4

• 580-13-2
• 59779-75-8

• 137365-09-4

Reference: [1]Current Patent Assignee: TIANJIN DERCHEMIST SCI TECH - CN107721969, 2018, A
Location in patent: Paragraph 0042; 0044
[2]Du, Haifeng; Zhao, Dongbo; Ding, Kuiling
[Chemistry - A European Journal, 2004, vol. 10, # 23, p. 5964 - 5970]
[3]Wang, Yin-Xia; Qi, Shao-Long; Luan, Yu-Xin; Han, Xing-Wang; Wang, Shan; Chen, Hao; Ye, Mengchun
[Journal of the American Chemical Society, 2018, vol. 140, # 16, p. 5360 - 5364]

Downstream Synthesis Route 5

• 90-11-9
• 59779-75-8

• 137536-94-8

Reference: [1]Patent: CN107721969,2018,A .Location in patent: Paragraph 0050; 0052

* For details of the synthesis route, please refer to the original source to ensure accuracy.