(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct

• CAS: 328123-04-2
• Catalog Number: ACM328123042
• Category: Other Products
• Molecular Weight: 718.535g/mol
• Molecular Formula: C37H45Cl2NO6Ti
• Synonyms: 328123-04-2;(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM (IV) DICHLORIDE;MFCD04973054;SC10833;Tetraphenyl-TADDOL-DME-titaniumdichloride;123D042;(4R,5R)-(-)-2,2-Di-Me-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(diMeO)ethane]Ti(IV) dichloride CH3CN adduct;(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato(1,2-bis(dimethoxy)ethane)titanium(IV) dichloride;(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
• IUPAC Name: acetonitrile;cyclohexa-1,3-dien-1-yl-[(4R,5R)-5-[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-phenylmethanol;dichlorotitanium;1,2-dimethoxyethane
• Canonical SMILES: CC#N.CC1(OC(C(O1)C(C2=CC=CC=C2)(C3=CC=CC=C3)O)C(C4=CC=CCC4)(C5=CC=CC=C5)O)C.COCCOC.Cl[Ti]Cl
• InChI: InChI=1S/C31H32O4.C4H10O2.C2H3N.2ClH.Ti/c1-29(2)34-27(30(32,23-15-7-3-8-16-23)24-17-9-4-10-18-24)28(35-29)31(33,25-19-11-5-12-20-25)26-21-13-6-14-22-26;1-5-3-4-6-2;1-2-3;;;/h3-13,15-21,27-28,32-33H,14,22H2,1-2H3;3-4H2,1-2H3;1H3;2*1H;/q;;;;;+2/p-2/t27-,28-,31 ;;;;;/m1...../s1
• InChI Key: YTJMLZYQYKUFOH-IWLCBTADSA-L
• Application: Catalyst used in the enantioselective fluorination of β-ketoesters.; ; Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others.
• Complexity: 829
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 2
• Exact Mass: 717.21g/mol
• H-Bond Acceptor: 7
• H-Bond Donor: 2
• Heavy Atom Count: 47
• Monoisotopic Mass: 717.21g/mol
• Rotatable Bond Count: 7
• Topological Polar Surface Area: 101A^2
• Undefined Atom Stereocenter Count: 1

Custom Reviews

February 6, 2023

---

Multi-purpose catalyst
As a catalyst, (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct can catalyze enantioselective addition reaction of carbonyl compounds, transfer reaction of allyl groups and cycloaddition reaction.

Custom Q&A

What is molecular formula of (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct?

C31H30Cl2O4Ti.C4H10O2.C2H3N

What is formula weight of (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct?

716.521

What is appearance shape of (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct?

Crystal

What is the color of (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct?

White

What is the sensitivity of (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct?

Air sensitive and moisture sensitive