4'-Aminobenzo-15-crown-5-ether

• CAS: 60835-71-4
• Catalog Number: ACM60835714-2
• Category: Other Products
• Molecular Weight: 283.32
• Molecular Formula: C14H21NO5
• Synonyms: (Benzo-15-crown-5)-4'-ylamine
• IUPAC Name: 2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-trien-17-amine
• Canonical SMILES: C1COCCOC2=C(C=C(C=C2)N)OCCOCCO1
• InChI Key: CQNGAZMLFIMLQN-UHFFFAOYSA-N
• Boiling Point: 464.4 ºC at 760 mmHg
• Melting Point: 76-78 °C-lit.
• Flash Point: 256 ºC
• Density: 1.118g/cm³
• Appearance: yellowish crystal
• Exact Mass: 283.14200
• Hazard Statements: Xi:Irritant
• H-Bond Acceptor: 6
• H-Bond Donor: 1
• Safety Description: S26-S36/37
• WGK Germany: 3

Synthetic Use

Downstream Synthesis Route 1

• 75-15-0
• 60835-71-4

• 128093-18-5

Reference: [1]Current Patent Assignee: PURDUE UNIVERSITY SYSTEM - WO2005/77962, 2005, A2
Location in patent: Page/Page column 62
[2]Granell, Jaume; Green, Malcolm L.H.; Lowe, Valerie J.; Marder, Seth R.; Mountford, Philip; et al.
[Journal of the Chemical Society, Dalton Transactions, 1990, # 2, p. 605 - 614]

Downstream Synthesis Route 2

• 112-16-3
• 60835-71-4

• 109065-13-6

Reference: [1]Shinkai, Seiji; Torigoe, Kazufumi; Manabe, Osamu; Kajiyama, Tisato
[Journal of the American Chemical Society, 1987, vol. 109, # 15, p. 4458 - 4464]

Downstream Synthesis Route 3

• 60835-71-4
• 89373-67-1

• 109065-12-5

Reference: [1]Shinkai, Seiji; Torigoe, Kazufumi; Manabe, Osamu; Kajiyama, Tisato
[Journal of the American Chemical Society, 1987, vol. 109, # 15, p. 4458 - 4464]
[2]Shinkai, Seiji; Torigoe, Kazufumi; Manabe, Osamu; Kajiyama, Tisato
[Journal of the Chemical Society. Chemical communications, 1986, # 12, p. 933 - 935]

* For details of the synthesis route, please refer to the original source to ensure accuracy.