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Structure

1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)

CAS
104439-77-2
Catalog Number
ACM104439772-1
Category
Ruthenium series catalysts
Molecular Weight
1084.1
Molecular Formula
C62H41O6Ru2

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Specification

Synonyms
Shvo's catalyst
Canonical SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)C2=C(C(=O)C(=C2C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5.C1=CC=C(C=C1)[C]2[C]([C]([C]([C]2C3=CC=CC=C3)O)C4=CC=CC=C4)C5=CC=CC=C5.[Ru].[Ru]
InChI
InChI=1S/C29H21O.C29H20O.4CO.2Ru/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;/h1-20,30H;1-20H;
InChI Key
LYADOKFHMFDLJK-UHFFFAOYSA-N
Melting Point
223-227 °C
Appearance
Powder
Application
In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.

Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.

Conversion of secondary amines to primary amines in the presence of ammonia.

Co-catalyt for aerobic lactonization of diols.
Exact Mass
1087.10008
Hydrogen Bond Acceptor Count
6
Hydrogen Bond Donor Count
1
Monoisotopic Mass
1085.098995
Rotatable Bond Count
8
Topological Polar Surface Area
41.3 Ų
January 20, 2023


Work well in preparing composite catalyst
The combination of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) and lipase can be used for asymmetric conversion of ketones and enolacetates.

What is the chemical name of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The chemical name of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) is 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II).

What is the product category of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The product category of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) is Ru.

What is a synonym for 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

One synonym is SHVO'S CATALYST.

What is the molecular weight of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The molecular weight of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) is 1084.13.

What is the color of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The compound is orange in color.

What is the melting point range of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The melting point range of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) is 223-227 °C.

What is the solubility of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The compound is slightly soluble in DMSO.

What safety statements are associated with 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The safety statements associated with 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) are 22-24/25.

What are the uses of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)?

The compound is used as a catalyst in organic syntheses for hydrogen transfers, including disproportionation of aldehydes, reduction of ketones and aldehydes, and oxidation and/or racemization of alcohols and amines.

How can 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) be used in reactions?

The compound can be used in conjugation with a lipase for the asymmetric transformation of ketones and enol acetates into chiral acetates, in dynamic kinetic resolution resulting from the ruthenium-catalyzed racemization of enzymatically resolved substrates, in the conversion of secondary amines to primary amines in the presence of ammonia, and as a co-catalyst for the aerobic lactonization of diols.

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